Gas Adsorption Equilibria,9780387235974

Gas Adsorption Equilibria

by ;
ISBN13: 9780387235974
ISBN10: 0387235973
Format: Hardcover
Pub. Date: 2004-11-30
Publisher(s): Springer Verlag
List Price: $249.99

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Summary

This book is intended to present for the first time experimental methods to measure equilibria states of pure and mixed gases being adsorbed on the surface of solid materials. It has been written for engineers and scientists from industry and academia who are interested in adsorption based gas separation processes and/or in using gas adsorption for characterization of the porosity of solid materials.

Table of Contents

Preface xi
Acknowledgements xiii
Introduction 1(1)
Introduction
1(1)
Gas Adsorption Processes in Separation Technology
2(4)
Experimental Methods
6(4)
What Is Not Considered
10(7)
References
11(6)
Basic Concepts
17(62)
Introduction
17(1)
Adsorption Phenomena
18(7)
Sorbent Materials
25(6)
Characterization of Porous Solids
31(21)
Mercury Intrusion Porosimetry
32(2)
Helium Measurements
34(9)
Gas Adsorption (N2, Ar, CO2)
43(9)
Mass and Volume of Adsorbed Phases
52(18)
Models for the Void Volume (Vs) of a Sorbent Material and the Volume (Va) of a Sorbate
56(10)
Outline of Calorimetric-Dielectric Measurements of Absolute Masses of Adsorbates
66(4)
List of Symbols
70(9)
References
72(7)
Volumetry / Manometry
79(38)
Introduction
79(2)
Volumetric Measurement of Pure Gas Adsorption Equilibria (N=1)
81(7)
Experimental
81(1)
Theory
82(3)
Uncertainties or Errors of Measurements
85(2)
Example
87(1)
Thermovolumetry
88(3)
Volumetric Measurement of Multicomponent Gas Adsorption Equilibria (N > 1)
91(6)
Experimental
91(1)
Theory
92(2)
Uncertainties or Errors of Measurements
94(1)
Example
95(2)
Volumetric -- Calorimetric Measurements The Sensor Gas Calorimeter (SGC)
97(12)
Experimental
99(4)
Outline of Theory and Calibration
103(3)
Example
106(3)
Pros and Cons of Volumetry / Manometry
109(2)
Advantages
109(1)
Disadvantages
109(2)
List of Symbols
111(6)
References
114(3)
Gravimetry
117(64)
Introduction
117(3)
Gravimetric Measurements of Pure Gas Adsorption Equilibria (N = 1)
120(33)
Two Beam Balances
120(1)
Experimental
120(2)
Theory
122(5)
Uncertainties or Errors of Measurements
127(2)
Single Beam Balances
129(1)
Experimental
129(2)
Theory
131(3)
Uncertainties or Errors of Measurements
134(1)
Examples
135(18)
Thermogravimetry
153(4)
Gravimetric Measurement of Multicomponent Gas Adsorption Equilibria (N>1)
157(10)
Experimental
157(1)
Theory
158(3)
Uncertainties or Errors of Measurement
161(1)
Examples
162(5)
Pros and Cons of Gravimetry
167(4)
Advantages
167(3)
Disadvantages
170(1)
List of Symbols and Abbreviations
171(10)
References
175(6)
Volumetric -- Gravimetric Measurements
181(54)
Introduction
181(1)
Volumetric -- Gravimetric Measurements of Binary Coadsorption Equilibria
182(23)
Experimental
182(3)
Theory
185(6)
Uncertainties or Errors of Measurement
191(2)
Examples
193(12)
Densimetric -- Gravimetric Measurements of Binary Coadsorption Equilibria
205(20)
Experimental
205(3)
Theory
208(5)
Uncertainties or Errors of Measurement
213(1)
Example
214(4)
Densimetric-Volumetric Measurements of Binary Coadsorption Equilibria
218(4)
Volumetric-Densimetric Measurements of Wall Adsorption
222(3)
Pros and Cons of Volumetric-Gravimetric Measurements of Binary Coadsorption Equilibria
225(4)
Advantages
225(1)
Disadvantages
226(1)
Comparison of Densimetric-Gravimetric and Densimetric-Volumetric Binary Coadsorption Measurements
227(2)
List of Symbols and Abbreviations
229(6)
References
232(3)
Oscillometry
235(52)
Introduction
235(2)
Measurement of Pure Gas Adsorption Equilibria (N = 1) by Slow Oscillations of a Rotational Pendulum
237(19)
Experimental
237(3)
Outline of Theory
240(1)
The Motion of the Pendulum in Vacuum
241(2)
The Motion of the Pendulum in Sorptive Gas
243(8)
Uncertainties or Errors of Measurement
251(1)
Examples
252(4)
Oszillometric -- Gravimetric Measurements of Gas Absorption in Swelling Materials
256(9)
Introductory Remarks
256(1)
Experimental
257(3)
Theory
260(3)
Example
263(2)
Oscillometric -- Manometric Measurements of Gas Absorption in Swelling Materials
265(10)
Introductory Remarks
265(1)
Experimental
266(5)
Theory
271(1)
Example
272(3)
Pros and Cons of Oscillometry
275(2)
Advantages
275(1)
Disadvantages
275(2)
List of Symbols
277(10)
References
282(5)
Impedance Spectroscopy
287(72)
Introduction
287(2)
Dielectric Measurements of Gas Adsorption Systems
289(43)
Experimental
289(10)
Theory
299(1)
Basic Concepts
299(3)
Polarization of Dielectrics
302(4)
Models for the Complex Permittivity of Dielectric Sorbent-Sorbate Systems
306(10)
Uncertainties of Dielectric Measurements of Adsorption Systems
316(2)
Examples
318(14)
Dielectric-Manometric and Dielectric-Gravimetric Measurements of Pure Gas Adsorption Equilibria
332(17)
Experimental
332(4)
Examples
336(6)
Impedance Measurements in Adsorption Reactors
342(7)
Pros and Cons of Impedance Spectroscopy
349(2)
Advantages
349(1)
Disadvantages
350(1)
List of Symbols
351(8)
References
353(6)
Adsorption Isotherms
359(56)
Introduction
359(4)
Simple Molecular Isotherms
363(19)
Langmuir Adsorption Isotherm
363(1)
Classical Form
363(9)
Heterogeneous Surfaces
372(5)
Admolecules with Interactions
377(5)
Empirical Isotherms
382(12)
Freundlich-Ostwald-Boedecker (FOB)
382(2)
Virial Expansions
384(2)
Toth's Isotherm
386(1)
Brunauer-Emmett-Teller Isotherm (BET)
387(4)
Dubinin-Polanyi Theory
391(2)
Integral Equation Approach
393(1)
Thermodynamic Isotherms
394(8)
Gibbs's Approach
394(1)
Internal Variable Approach
395(7)
Conclusions
402(2)
List of Symbols
404(11)
References
407(8)
Subject Index 415(6)
Author Index 421

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