Hydroxyoximes and Copper Hydrometallurgy

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Format: Hardcover
Pub. Date: 1993-06-11
Publisher(s): CRC Press
List Price: $550.00

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Summary

Hydroxyoximes and Copper Hydrometallurgy provides a current examination of what is known regarding hydroxyoxime extractants, the chemistry and physicochemistry of extraction, and the potential of applying hydroxyoximes for extraction of copper and other metals in industrial processes. Topics addressed include the development of the hydrometallurgical process, methods of synthesis and structural characteristics, extraction properties, losses of active substances and problems associated with environmental pollution, the potential of metal extraction and separation with hydroxyoximes, methods of extraction and stripping that can improve metal separation and recovery, the applications of hydroxyoximes in various membrane processes, and industrial processes and equipment used for processing oxide ores and tailing. The book will benefit metallurgists, hydrometallurgists, analytical and physical chemists, and researchers in mining industries and solvent extraction.

Table of Contents

Development of Hydrometallurgical Processesp. 1
Industrial Hydroxyoxime Extractants and Their Characteristicsp. 13
Review of Extractantsp. 14
Extraction Properties of Commercial Extractantsp. 61
Loss of Active Substance and Problems Associated With Environmental Pollutionp. 91
Physicochemistry of Metal Extraction With Hydroxyoximesp. 103
Structure of Metal-Hydroxyoxime Complexesp. 104
Dissociation and Association of Hydroxyoximes and Stability of Their Complexes With Metalsp. 117
Partition and Interfacial Activity of Hydroxyoximesp. 145
Equilibrium Studies of Metal Extraction from Diluted Solutionsp. 169
Kinetics and Mechanism of Copper Extraction With Hydroxyoximesp. 211
Extraction With Hydroxyoximes Containing a Phenolic Groupp. 211
Catalysis in Hydroxyoxime Systemsp. 243
Diluents and Their Role in Metal Extraction With Hydroxyoximesp. 261
Potential of Metal Extraction and Separation With Hydroxyoximesp. 277
Extraction from Systems Containing a Single Metalp. 278
Extraction of Copper, Nickel, and Cobaltp. 278
Extraction of Other Metalsp. 301
Separation of Metalsp. 311
Application of Hydroxyoximes in Membrane Processesp. 345
Processing of Copper Oresp. 367
General Characteristicsp. 368
Processing of Ores and Oxide Tailingsp. 387
Processing of Sulfide Oresp. 401
Indexp. 415
Table of Contents provided by Blackwell. All Rights Reserved.

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