Ternary Phase Diagrams in Materials Science,9781902653525

Ternary Phase Diagrams in Materials Science

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Edition: 3rd
ISBN13: 9781902653525
ISBN10: 1902653521
Format: Hardcover
Pub. Date: 2002-03-01
Publisher(s): CRC Press
List Price: $185.00

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Summary

The objective of this new edition is to serve a wide range of readers, particularly undergraduates, and post-graduates and those scientists already established in their careers, who wish to acquire or extend their understanding of ternary phase diagrams. The extended coverage includes discussion of a wider range of materials, a new chapter reviewing thermodynamic principles and a problem and answer section.

Table of Contents

Foreword viii
Acknowledgements x
Preface to the First Edition xi
Preface to the Second Edition xii
General Considerations
1(12)
Introduction
1(1)
The Phase Rule
1(1)
The Ternary Space Model
2(6)
Phases and Their Equilibria
8(3)
One Phase is Present
9(1)
Two Phases Co-Exist
9(1)
Three Phases Co-Exist
10(1)
Four Phases Co-Exist
11(1)
Classification and Features of Ternary Metallic and Ceramic Systems
11(1)
Problem
12(1)
Some Thermodynamic Considerations for Phase Equilibria and Transformations
13(18)
Introduction
13(2)
Binary and Ternary Solutions
15(5)
Calphad (Calculation of Phase Diagrams)
20(4)
Topological Features of Phase Diagrams Calculated Using Regular Solution Theory
24(2)
Features of Phase Diagrams in Binary Polymeric Systems
26(5)
Systems Containing Two Phases
31(4)
Problem
34(1)
Systems Containing Three Phases
35(28)
Introduction
35(1)
Systems Containing A Eutectic Reaction L + α → β
35(8)
The Eutectic Reaction
36(2)
Projected View of the System
38(3)
Isothermal Sections
41(1)
Vertical Section
41(2)
Systems Containing a Peritectic Reaction L → α + β
43(6)
The Peritectic Reaction
44(2)
Projected View of the System
46(2)
Isothermal Sections
48(1)
Vertical Section
48(1)
Transition Between Eutectic and Peritectic Three-Phase Reactions
49(3)
Systems Containing a Monotectic Reaction L1 → L2 + α
52(4)
Systems Containing a Solid State Miscibility Gap that Closes within the System
56(3)
Miscibility Gaps in Ternary Polymeric Systems
59(1)
Problems
60(3)
Systems Containing Four Phases
63(22)
Introduction
63(1)
Systems Containing a Ternary Eutectic Reaction (Class I)
64(7)
A System in Which the Three Binary Systems are of the Eutectic Type
64(2)
Projected View of the System
66(1)
The Solidification of Alloys
67(2)
Isothermal Sections
69(1)
A System in Which One of the Binary Systems is of the Peritectic Type and Two are of the Eutectic Type
69(2)
Systems Containing a Ternary Peritectic Reaction (Class II and Class III)
71(10)
A System in Which One Binary System is of the Peritectic Type, and Two are of the Eutectic Type, and Which Shows an Invariant Reaction of the Type L + α → β + γ (Class II)
71(4)
Projected View of the System
75(1)
The Solidification of Alloys
76(1)
Isothermal Sections
77(1)
A System in Which One Binary System is of the Eutectic Type, and Two are of the Peritectic Type, and Which Shows an Invariant Reaction of the Type L + α → β + γ (Class III)
78(2)
Projected View of the System
80(1)
The Solidification of Alloys
81(1)
Isothermal Section
81(1)
Problems
81(4)
Systems Containing More Than Four Phases
85(16)
Introduction
85(1)
An Intermediate Phase Stable up to its Melting Point (i.e. Congruently Melting) Exists in One of the Binary Systems
85(6)
An Intermediate Phase Formed by a Peritectic Reaction Exists in One of the Binary Systems
91(1)
More than One Binary Intermediate Phase Exists in the System
91(5)
Ternary Intermediate Phases are Present
96(1)
Problems
97(4)
Principles of Using Liquidus Projections for Equilibrium and Non-Equilibrium Solidification in Metallic and Ceramic Systems
101(12)
Introduction
101(1)
Primary Phase Fields on a Liquidus Projection
102(1)
Curves on a Liquidus Projection
102(1)
Points on Liquidus Projections
103(2)
Non-Equilibrium Solidification
105(3)
Quantitative Approach to Non-Equilibrium Solidification
108(5)
Selected Case Studies of Ternary Systems
113(74)
Nb-Ta-C
113(1)
Ga-As-Zn
114(2)
Au-Pb-Sn
116(2)
Ni-Al-Cr, Ni-Al-Ti and Ni-Cr-Al-Ti
118(6)
Fe-Cr-C, Fe-Cr-Ni and Fe-Cr-Ni-C
124(12)
Fe-Cr-C
124(1)
Fe-Cr-Ni
125(9)
Fe-Cr-Ni-C
134(2)
Fe-O-Si
136(16)
Fe-O-S
152(1)
Ag-Pb-Zn
153(5)
Al-Fe-Si, Al-Fe-Mn, Al-Mn-Si and Al-Fe-Mn-Si
158(9)
Al-Fe-Si
159(3)
Al-Fe-Mn
162(4)
Al-Mn-Si
166(1)
Al-Fe-Mn-Si
166(1)
Ti-Al Based Alloys
167(8)
Al2O3-MgO-SiO2 (Corundum-Periclase-Cristobalite/Tridymite)
175(4)
BaO-CuO-YO1.5
179(8)
Answers to Problems
187(22)
Reviews and Compendiums of Experimental Phase Diagram Determination, Current Activities in Phase Diagram Determination and Information Regarding Software Packages for the Thermodynamic Calculation of Phase Equilibria
209(6)
Source References
211(4)
References 215(4)
Index 219(4)
Graph Paper for Calculations 223

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